Magnetic Spinel-Type CoFe2O4 Nanoparticles: Synthesis and Investigation of Structural, Morphological Properties

Mesut ÖZDİNÇER, Sefa DURMUŞ, Aslıhan DALMAZ
496 141

Öz


Spinel-type metal oxide nanoparticles were synthesized via co-precipitation approach. Mono ethylene glycol (MEG) was used as a capping agent to stabilize the particles and prevent them from agglomeration. The structural, morphological and thermal properties of the calcined sample were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), raman spectroscopy and thermal analysis. Energy-dispersive X-ray analysis (EDX) has also proved that the element composition was composed of pure single phase and contained Co, Fe and O elements. The mean crystallite size of the prepared ferrite nanoparticles was determined to be in the range of 30-345 nm based on the SEM images. The magnetic measurements of the CoFe2O4 nanoparticles were examined with a vibrating sample magnetometer (VSM) at room temperature to determine their magnetic behavior and the magnetic parameters were found.

Anahtar kelimeler


CoFe2O4; Ferrite; Nanoparticles; Raman; SEM; Spinel

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DOI: http://dx.doi.org/10.19113/sdufbed.61527

Referanslar


[1] Sener, T., Kayhan, E., Sevim, M., Metin, O. 2015. Monodisperse CoFe2O4 Nanoparticles Supported on Vulcan XC-72: High Performance Electrode Materials for Lithium-Air and Lithium-Ion Batteries. Journal of Power Sources, 288, 36-41.

[2] Ding, Y., Yang, Y. F., Shao, H. X. 2013. One-Pot Synthesis of NiFe2O4/C Composite as an Anode Material for Lithium-Ion Batteries. Journal of Power Sources, 244, 610-613.

[3] Rai, A. K., Thi, T. V., Gim, J., Mathew, V., Kim, J. 2014. Co1-xFe2+xO4 (x=0.1, 0.2) Anode Materials for Rechargeable Lithium-Ion Batteries. Solid State Sciences, 36, 1-7.

[4] Zhang, M., Lu, J., Zhang, J. N., Zhang, Z. H. 2016. Magnetic Carbon Nanotube Supported Cu (CoFe2O4/CNT-Cu) Catalyst: A Sustainable Catalyst for the Synthesis of 3-nitro-2-arylimidazo[1,2-a]pyridines. Catalysis Communications, 78, 26-32.

[5] El-Remaily, M. A. A. A., Hamad, H. A. 2015. Synthesis and Characterization of Highly Stable Superparamagnetic CoFe2O4 Nanoparticles as a Catalyst for Novel Synthesis of thiazolo[4,5-b]quinolin-9-one Derivatives in Aqueous Medium. Journal of Molecular Catalysis A-Chemical, 404, 148-155.

[6] Liu, F. J., Laurent, S., Roch Vander Elst, L., Muller, R. N. 2013. Size-Controlled Synthesis of CoFe2O4 Nanoparticles Potential Contrast Agent for MRI and Investigation on Their Size-Dependent Magnetic Properties. Journal of Nanomaterials, 2013, 1-9.

[7] Sanpo, N., Berndt, C. C., Wen, C., Wang, J. 2013. Transition Metal-Substituted Cobalt Ferrite Nanoparticles for Biomedical Applications. Acta Biomaterialia, 9, 5830-5837.

[8] Zhao, L., Zhang, H., Xing, Y., Song, S., Yu, S., Shi, W., Guo, X., Yang, J., Lei, Y., Cao, F. 2008. Studies on the Magnetism of Cobalt Ferrite Nanocrystals Synthesized by Hydrothermal Method. Journal of Solid State Chemistry, 181, 245-252.

[9] Maaz, K., Mumtaz, A., Hasanain, S. K., Ceylan, A. 2007. Synthesis and Magnetic Properties of Cobalt Ferrite (CoFe2O4) Nanoparticles Prepared by Wet Chemical Route. Journal of Magnetism and Magnetic Materials, 308, 289-295.

[10] Lima, A. C., Morales, M. A., Araujo, J. H., Soares, J. M., Melo, D. M. A., Carrico, A. S. 2015. Evaluation of (BH)(max) and Magnetic Anisotropy of Cobalt Ferrite Nanoparticles Synthesized in Gelatin. Ceramics International, 41, 11804-11809.

[11] Yardımcı, F. S., Şenel, M., Baykal, A. 2012. Amperometric Hydrogen Peroxide Biosensor Based on Cobalt Ferrite–Chitosan Nanocomposite. Materials Science and Engineering: C, 32, 269-275.

[12] Tong, J., Bo, L., Li, Z., Lei, Z., Xia, C. 2009. Magnetic CoFe2O4 Nanocrystal: A Novel and Efficient Heterogeneous Catalyst for Aerobic Oxidation of Cyclohexane. Journal of Molecular Catalysis A: Chemical, 307, 58-63.

[13] Rajput, J. K., Kaur, G. 2013. CoFe2O4 Nanoparticles: An Efficient Heterogeneous Magnetically Separable Catalyst for "click" Synthesis of Arylidene Barbituric Acid Derivatives at Room Temperature. Chinese Journal of Catalysis, 34, 1697-1704.

[14] Xu, C., Sun, S. 2013. New Forms of Superparamagnetic Nanoparticles for Biomedical Applications. Advanced Drug Delivery Reviews, 65, 732-743.

[15] Raghasudha, M., Ravinder, D., Veerasomaiah, P. 2016. Investigation of Superparamagnetism in Pure and Chromium Substituted Cobalt Nanoferrite. Journal of Magnetism and Magnetic Materials, 420, 45-50.

[16] Dong, N., Zhong, M., Fei, P., Lei, Z. Q., Su, B. T. 2016. Magnetic and Electrochemical Properties of PANI-CoFe2O4 Nanocomposites Synthesized via a Novel One-Step Solvothermal Method. Journal of Alloys and Compounds, 660, 382-386.

[17] Ansari, S., Arabi, H., Sadr, S. M. A. 2016. Structural, Morphological, Optical and Magnetic Properties of Al-Doped CoFe2O4 Nanoparticles Prepared by Sol-Gel Auto-Combustion Method. Journal of Superconductivity and Novel Magnetism, 29, 1525-1532.

[18] Feng, H. X., Chen, B. Y., Zhang, D. Y., Zhang, J. Q., Tan, L. 2014. Preparation and Characterization of the Cobalt Ferrite Nano-Particles by Reverse Coprecipitation. Journal of Magnetism and Magnetic Materials, 356, 68-72.

[19] Naseri, M. G., Saion, E. B., Hashim, M., Shaari, A. H., Ahangar, H. A. 2011. Synthesis and Characterization of Zinc Ferrite Nanoparticles by a Thermal Treatment Method. Solid State Communications, 151, 1031-1035.

[20] Rashidi, S., Ataie, A. 2016. Structural and Magnetic Characteristics of PVA/CoFe2O4 NanoComposites Prepared via Mechanical Alloying Method. Materials Research Bulletin, 80, 321-328.

[21] Briceño, S., Brämer-Escamilla, W., Silva, P., Delgado, G. E., Plaza, E., Palacios, J., Cañizales, E. 2012. Effects of Synthesis Variables on the Magnetic Properties of CoFe2O4 Nanoparticles. Journal of Magnetism and Magnetic Materials, 324, 2926-2931.

[22] Chandramohan, P., Srinivasan, M. P., Velmurugan, S., Narasimhan S. V. 2011. Cation Distribution and Particle Size Effect on Raman Spectrum of CoFe2O4. Journal of Solid State Chemistry, 184, 9-96.

[23] Teixeiraa, A. M. R. de F., Ogasawarab, T. Nóbrega, M. C. de S. 2006 Investigation of Sintered Cobalt-zinc Ferrite Synthesized by Coprecipitation at Different Temperatures: A Relation between Microstructure and Hysteresis Curves. Materials Research, 9, 257-262.

[24] Dey, S., Ghose, J. 2003. Synthesis, Characterisation and Magnetic Studies on Nanocrystalline Co0.2Zn0.8Fe2O4. Materials Research Bulletin, 38, 1653–1660.




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